4.6 Article

Tandem metal relay catalysis: from cyclopropene to polysubstituted furan

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 31, Pages 5802-5806

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob00987h

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Funding

  1. Natural Science Foundation of China [21102085]
  2. Ministry of Education of China [20110131120049]
  3. Shandong University [2014JC008]

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Transmetalation is a key step in traditional coupling reactions. Herein we discuss the most recent progress in the Metal metal relay catalysis based on a transmetalation strategy. An efficient synthetic strategy for the formation of polysubstituted furan derivatives from cyclopropenes based on the tandem metal relay catalysis (TMRC reaction) is summarized.

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