4.6 Article

Copper-mediated trifluoromethylation of propargyl acetates leading to trifluoromethyl-allenes

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 18, Pages 2903-2906

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob42575d

Keywords

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Funding

  1. National Natural Science Foundation [21032006, 21172240]
  2. 973 Program of China [2012CBA01200]
  3. Chinese Academy of Sciences
  4. Syngenta PhD Studentship Award

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A copper-mediated trifluoromethylation of propargyl acetates with S-(trifluoromethyl)diphenylsulfonium triflate leading to trifluoromethylated allenes in moderate to excellent yields is described.

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