4.6 Article

Synthesis and spectroscopic properties of novel meso-cyano boron-pyridyl-isoindoline dyes

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 41, Pages 8223-8229

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob01077a

Keywords

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Funding

  1. National Natural Science Foundation of China [21101049, 21471042, 51353003]
  2. Zhejiang Provincial Natural Science Foundation of China [LY14B010003]
  3. Grants-in-Aid for Scientific Research [23350095] Funding Source: KAKEN

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meso-Cyano boron-pyridyl-isoindoline dyes with asymmetrical structures were synthesized through a facile two-step reaction. Broad envelopes of intense vibrational bands were observed for the main spectral bands in the absorption and emission spectra. Moderate fluorescence quantum yields were obtained in solution, with significant intensity also observed in film, powder and crystal forms. An analysis of the structure-property relationships was carried out based on X-ray crystallography, optical spectroscopy, and theoretical calculations.

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