Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 14, Pages 2280-2288Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob42276c
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An expedient synthesis of N-unsubstituted 1,2,3-triazole-4-carboxylates has been demonstrated through [3 + 2] cycloaddition of sodium azide with alpha-haloacrylates. The process is highly reliable and exhibits an unusually wide scope with respect to alpha-fluoro-, alpha-chloro-, alpha-bromo-, and alpha-iodoacrylates. The potential of selected 1,2,3-triazole-4-carboxylates in the preparation of 1,5-dihydro-4H-[1,2,3]-triazolo-[4,5-c]-quinolin-4-one has also been illustrated.
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