Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 46, Pages 9453-9456Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob01524j
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Funding
- CSIR [CS-0123 INDUS MAGIC]
- UGC New Delhi, India
- DST, Govt. India [SR/S1/OC-13/2011]
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Oxidative esterification of benzylic alcohols with a catalytic amount of HBr-H2O2 in aqueous medium under mild conditions is reported with a wide range of substrate scope for both benzylic and aliphatic alcohols. The conditions are also suitable for selective mono-esterification of ethylene glycol and glycerol. With catalytic amounts of HBr (20 mol%) and H2O2, the generation of reactive intermediate species BrOH has been ascertained by UV-visible spectra.
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