Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 25, Pages 4324-4328Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob00888j
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Funding
- National Science Foundation of China [21325206, 21172006]
- National Young Topnotch Talent Support Program
- Ph.D. Programs Foundation of the Ministry of Education of China [20120001110013]
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A novel and efficient approach to alkenyl nitriles from readily available propargylic alcohols has been developed. This nitrogenation reaction is transition-metal-free and could be conducted under air at ambient temperature, which makes this protocol promising and practical. Moreover, NH4Br is disclosed as an efficient additive to promote the stereoselectivity of this reaction.
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