Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 33, Pages 6414-6424Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob01041h
Keywords
-
Categories
Funding
- National Basic Research Program of China [2009CB825300]
- National Natural Science Foundation of China [21172208]
Ask authors/readers for more resources
P,N,N-Pincer nickel complexes [Ni(Cl){N(2-R2PC6H4)(2'-Me2NC6H4)}] (R = Ph, 3a; R = Pr-i, 3b; R = Cy, 3c) were synthesized and their catalysis toward the Kumada or Negishi cross-coupling reaction of aryl fluorides and chlorides was evaluated. Complex 3a effectively catalyzes the cross-coupling of (hetero)aryl fluorides with aryl Grignard reagents at room temperature. Complex 3a also catalyzes the cross-coupling of (hetero) aryl chlorides and arylzinc reagents at 80 degrees C with low catalyst loadings and good functional group compatibility.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available