Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 11, Issue 43, Pages 7463-7466Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob41782d
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Centre in Green Chemistry and Catalysis (CGCC)
- Canada Foundation for Innovation (CFI)
- Universite Laval
- NSERC
- Fonds Quebecois de la Recherche Nature et technologies (FQRNT)
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A highly enantioselective method for the catalytic cis-stilbene oxide opening reaction with indole derivatives was developed. The scope of the reaction was studied with a selection of aromatic meso-epoxides and various indoles, and the desired 2-(indol-3-yl)ethanol derivatives were obtained in good to excellent yields with excellent enantioselectivities (from 96 to >99% ee).
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