Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 11, Issue 5, Pages 709-716Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob26681d
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Funding
- Birla Institute of Technology and Science, Pilani
- Department of Science and Technology (DST)-New Delhi [SR/FT/CS-109/2011]
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Amine catalysis, through HOMO-activating enamine and LUMO-activating iminium-ion formation, is receiving increasing attention among other organocatalytic strategies, for the activation of unmodified carbonyl compounds. Particularly, the HOMO-raising activation concept has been applied to the greatest number of asymmetric transformations through enamine, dienamine, and SOMO-activation strategies. Recently, trienamine catalysis, an extension of amine catalysis, has emerged as a powerful tool for synthetic chemists with a novel activation strategy for polyenals/polyenones. In this review article, we discuss the initial developments of trienamine catalysis for highly asymmetric Diels-Alder reactions with different dienophiles and emerging opportunities for other types of cycloadditions and cascade reactions.
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