4.6 Article

A novel neutral organic electron donor with record half-wave potential

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 11, Issue 46, Pages 8073-8081

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob41701h

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Funding

  1. University of Strathclyde
  2. Scottish Funding Council
  3. BAE Systems
  4. EPSRC [EP/I501177/1, EP/K033077/1] Funding Source: UKRI
  5. Engineering and Physical Sciences Research Council [EP/K033077/1, EP/I501177/1] Funding Source: researchfish

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Tricyclic donor 26 has been prepared and is the most reducing neutral ground-state organic molecule known, with an oxidation potential 260 mV more negative than the previous record. Cyclic voltammetry shows that a 2-electron reversible redox process occurs in DMF as solvent at -1.46 V vs. Ag/AgCl.

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