4.6 Article

Aromatic C-H silylation of arenes with 1-hydrosilatrane catalyzed by an iridium(I)/2,9-dimethylphenanthroline (dmphen) complex

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 11, Issue 47, Pages 8162-8165

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob41623b

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan [17065001]
  2. Grants-in-Aid for Scientific Research [17065001] Funding Source: KAKEN

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Aromatic C-H silylation of neat arenes with 1-hydrosilatrane was found to be efficiently catalyzed by iridium catalysts composed of 1/2[Ir(OMe)(cod)]2 and 2,9-dimethyl-1,10-phenanthroline at 120 degrees C to afford the corresponding silylated products in high yields. The silylated products can be used for the Hiyama cross-coupling reaction.

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