4.6 Article

Modular synthesis of all-substituted furans through oxidative carbonylation of cyclopropenes with tandem metal relay catalysis

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 11, Issue 37, Pages 6258-6262

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob41155a

Keywords

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Funding

  1. Natural Science Foundation of China [21102085]
  2. Science Foundation of the Ministry of Education of China [20110131120049]
  3. Natural Science Foundation of Shandong Province [BS2012YY006]
  4. Shandong University

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A modular synthesis of tetrasubstituted furan carboxylates using a tandem cycloisomerization/oxidative carbonylation sequence of cyclopropenes has been successfully developed. The Tandem Metal Relay Catalysis (TMRC) pathway accounted for the high efficiency of this transformation.

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