Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 11, Issue 35, Pages 5787-5792Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob41245h
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Funding
- China NSFC [21002018, 21072038]
- SKLUWRE [2012DX10]
- Fundamental Research Funds for the Central Universities [HIT.BRETIV.201310]
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A novel and simple procedure was developed for the regioselective synthesis of a-bromo (di)ketones from electron-rich epoxides via visible light photoredox catalysis. Through optimization of solvent and light source, the reaction can be rapidly achieved under mild conditions. Moreover, the possible reaction mechanism was proposed and further supported by control experiments.
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