4.6 Article

Host-guest complexation driven dynamic supramolecular self-assembly

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 11, Issue 13, Pages 2070-2074

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob27340c

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Funding

  1. Singapore National Research Foundation Fellowship [NRF2009NRFRF001-015]
  2. Singapore National Research Foundation CREATE program - Singapore Peking University Research Centre for a Sustainable Low-Carbon Future
  3. Nanyang Technological University

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Host-guest complexation between pillararene trimer 1 and biviologen 2 was used to fabricate the dynamic supramolecular self-assembly, which exhibits a reversible multidimensional transformation from 0D to 3D upon concentration changes. As a comparison, assemblies built by the complexation between 1,4-dimethoxypillar[5]arene and 2 only show spherical morphology under similar conditions.

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