Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 11, Issue 19, Pages 3094-3097Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob40232k
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Funding
- Chinese NSF [2097209, 21172140]
- Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning, Shanghai Education Committee [10YZ04]
- Shanghai Leading Academic Discipline Project [S30107]
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This paper highlights Ni-catalyzed allylation of electron-rich aryl bromides with a variety of substituted allylic carbonates using zinc as the terminal reductant, affording E-alkenes regioselectively in good to excellent yields by the addition of aryl to the less hindered allylic carbon. The electron-deficient aryl bromides and chlorides are also highly efficient coupling partners.
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