Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 1, Pages 134-145Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob06010d
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Funding
- EPSRC [EP/F019424, EP/G01244X/1]
- Warwick University
- EPSRC [EP/F019424/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G01244X/1, EP/F019424/1] Funding Source: researchfish
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The preparation of a range of asymmetric iron and ruthenium-cyclone complexes, and their application to the asymmetric reduction of a ketone, are described. The enantioselectivity of ketone reduction is influenced by a single chiral centre in the catalyst, as well as by the planar chirality in the catalyst. This represents the first example of asymmetric ketone reduction using an iron cyclone catalyst.
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