Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 17, Pages 3393-3397Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25251a
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Funding
- National Natural Science Foundation of China [20902057, 21002061, 21142012]
- State Key Laboratory of Applied Organic Chemistry, Lanzhou University
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The complexation of neutral 1,4-dihalobutanes with simple pillar[5]arenes was investigated. The results indicate the formation of interpenetrated complexes, where the dispersive interactions dominate the complex stability. Typically, 1,4-diiodobutane displays the strongest binding strength with ethylpillar[5]arene [K-a = (1.0 + 0.1) x 10(4) M-1], up to 120 fold as compared with 1,4-difluorobutane.
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