Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 16, Pages 3168-3171Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25235j
Keywords
-
Categories
Funding
- Department of Science and Technology Foundation of Hunan Province [2009WK4005]
- Hunan Nature Science Foundation [11JJ5008]
- Changsha Science and Technology [K082152-31]
- NSF [CAREER CHE-0969157]
Ask authors/readers for more resources
alpha-Oxo gold carbenes generated via intermolecular oxidation of terminal alkynes are shown to be highly electrophilic and can effectively abstract halogen from halogenated solvents such as 1,2-dichloroethane or 1,2-dibromoethane. Chloro/bromomethyl ketones are prepared in moderate efficiencies in one step using Ph3PAuNTf2 as the catalyst and 8-methylquinoline N-oxide as the oxidant.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available