Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 17, Pages 3357-3378Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob06731e
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Funding
- Fundacao para a Ciencia e Tecnologia
- FEDER [PTDC/QUI-QUI/099389/2008, PTDC/QUI/70902/2006, SFRH/BPD/46589/2008, PEst-OE/SAU/UI4013/2011]
- Fundação para a Ciência e a Tecnologia [SFRH/BPD/46589/2008, PTDC/QUI/70902/2006] Funding Source: FCT
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Dirhodium(II) catalysts have been widely used as a remarkable tool in organic synthesis, ultimately resulting in a myriad of transformations and formation of a wide variety of compounds, every so often intermediaries in drug synthesis. Aiming at a more sustainable chemistry, several methods suitable for the reutilisation of expensive dirhodium complexes have been developed. Herein, we provide a combined overview of the available methods for recovering and reusing dirhodium(II) metal complexes in catalysis, covering homogeneous catalysis as well as heterogenisation methods.
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