4.6 Article

Metallic organophosphates as catalysts in asymmetric synthesis: a return journey

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 26, Pages 5001-5020

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25479d

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Funding

  1. Spanish Government [CTQ-2009-12168]
  2. CAM [AVANCAT CS2009/PPQ-1634]
  3. MICINN

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This perspective article provides a general overview of the most relevant topics in the applications of chiral metallic organophosphates. A brief introduction along with a historic comparative profile of the BINOL and phosphoric acid analogues are given. Next, a selection of the most outstanding uses of the catalysts according to the employed metal is presented.

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