4.6 Article

The DNA three-way junction as a mould for tripartite chromophore assembly

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 4, Pages 755-759

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob06400b

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Funding

  1. Swiss National Foundation [200020-132581]
  2. Swiss National Science Foundation (SNF) [200020_132581] Funding Source: Swiss National Science Foundation (SNF)

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The DNA three-way junction serves as a scaffold for the molecular organization of non-nucleosidic alkynylpyrene and perylenediimide chromophores located at the branch point of the structure. Depending on the composition of the tripartite assembly, the constructs possess distinct spectroscopic properties, ranging from monomer or excimer fluorescence to completely quenched tripartite aggregates.

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