4.6 Article

Studies on a novel class of triaryl pyridine N-glycosylamine amphiphiles as super gelators

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 10, Pages 2077-2083

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob06834f

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Funding

  1. SERC-DST, New Delhi, India
  2. National Centre for Nanoscience and Nanotechnology, University of Madras, Chennai, India
  3. UGC, New Delhi, India

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A novel class of six different triaryl pyridine N-glycosylamine amphiphiles was synthesised and characterized based on different spectral techniques, such as NMR and mass analysis. Gelation properties in different aromatic and aliphatic solvents were studied and gelation was observed predominantly in aliphatic solvents with CGC of 0.5% (w/v) and is attributed to the presence of long alkyl chain. All the gels thus obtained were studied using FE-SEM and powder XRD techniques which reveal fibrous entanglement of the molecules in the gel state with intermolecular spaces of 3.62 nm and 0.43 nm.

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