4.6 Article

Palladium-catalyzed atom transfer radical cyclization of unactivated alkyl iodide

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 36, Pages 7274-7277

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25990g

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A palladium-catalyzed atom transfer cyclization of unactivated alkyl iodide has been developed. A radical chain mechanism has been proposed for this transformation, which might not involve an alkylpalladium intermediate.

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