Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 29, Pages 5521-5524Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25773d
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Funding
- Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- NSFC [21072188]
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[RhCp*Cl-2](2) can catalyze the oxidative coupling of secondary isonicotinamides with activated olefins using Cu(OAc)(2) as an oxidant. The selectivity can be controlled by the solvent. In MeCN, the mono-olefination and two-fold oxidation reaction is the major pathway, while in THF this reaction gave mostly diolefination products. In both cases, the coupled products contain an exocyclic C=C bond.
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