Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 27, Pages 5266-5277Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25124h
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- Jacobs University Bremen
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We report on a diastereoselective synthesis of six derivatives of caffeoyl- and feruloyl-muco-quinic acids. All the muco-quinic acid derivatives were obtained in excellent yield in five steps starting from quinic acid, caffeic acid and ferulic acid. Allyl ether protection of trans-hydroxy cinnamic acids was here introduced to chlorogenic acids synthesis. We show that muco-quinic acid derivatives, which are formally diastereoisomers of chlorogenic acids, can be readily distinguished by their tandem mass spectra.
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