Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 22, Pages 4327-4329Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25459j
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Funding
- Max-Planck-Society
- Max-Planck-Institut fur Kohlenforschung
- Deutsche Forschungsgemeinschaft (DFG) [4861/4-1]
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A new protocol for the direct two-electron oxidative Umpolung of alkali halide salts is reported. This procedure, relying on the use of a commercially available sulfoxide as the oxidant, allows the electrophilic halogenation of carbonyl compounds as well as halolactonisation reactions to proceed from the corresponding sodium salts, at room temperature and under mild conditions.
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