Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 35, Pages 7167-7176Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25755f
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Funding
- Spanish MEC [CTQ2009-07738/BQU]
- FUSP-CEU
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2-Allyl-1-vinyl-beta-carbolines and dihydropyrrolo-beta-carbolines react with activated internal alkynes through novel rearrangement reactions leading to complex polycyclic structures. Favored reaction pathways depend on reaction conditions and on the presence of gold catalysts. In particular, upon reaction with 2 equiv. of the alkyne, new hexacyclic structures 10 are formed with total stereocontrol.
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