Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 32, Pages 6526-6536Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25760b
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Funding
- FWO (Fund for Scientific Research - Flanders)
- KU Leuven
- Ministerie voor Wetenschapsbeleid
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Homoselenacalix[4]arenes were synthesized by a [2 + 2] reductive coupling protocol favouring the cyclotetramers. The inner and outer-rim decoration was varied and a bicyclic derivative was prepared by a similar one-pot procedure. Conformational analysis in solution and the solid state showed noticeable differences between the homoselenacalix[4]arenes and the analogous homothiacalix[4]arenes and provided insight into the metal binding potential of the Se-bridged macrocycles. The homoselenacalix[4]arenes were found to bind Ag(I). Complexation was visualized in the solid state and different packing networks were formed depending on the counter ions applied.
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