Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 9, Issue 7, Pages 2258-2265Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00722f
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Funding
- The National Natural Science Foundation of China [20572046, 20872064]
- Program for New Century Excellent Talents in University [NCET-07-0461]
- Tianjin Natural Science Foundation [09JCY-BJC05900]
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Catalytic oxidation of benzylic C-H bonds could be efficiently realized using IBS as a catalyst which was generated in situ from the oxidation of sodium 2-iodobenzenesulfonate (1b) by Oxone in the presence of a phase-transfer catalyst, tetra-n-butylammonium hydrogen sulfate, in anhydrous acetonitrile at 60 degrees C. Various alkylbenzenes, including toluenes and ethylbenzenes, several oxygen-containing functionalities substituted alkylbenzenes, and a cyclic benzyl ether could be efficiently oxidized. And, the same reagent system of cat. 1b/Oxone/cat. n-Bu4NHSO4 could be applied to the effective oxidation of alkanes as well.
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