4.6 Article

Iron-catalyzed sulfonyl radical formations from sulfonylhydrazides and oxidative addition to alkenes

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 9, Issue 9, Pages 3151-3153

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob01119c

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology of Japan

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Generation of sulfonyl radicals from sulfonylhydrazides has been achieved in the presence of a non-toxic iron catalyst and oxygen. The intermolecular addition of resultant sulfonyl radicals to alkenes affords beta-hydroxysulfone compounds.

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