Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 9, Issue 7, Pages 2057-2061Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob01088j
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- Japan Society for the Promotion of Science (JSPS)
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oxidative cyclisation provides an efficient approach to pyrano[3,2-a]carbazole alkaloids. Thus, improved routes to girinimbine and murrayacine as well as the first total syntheses of O-methylmurrayamine A and 7-methoxymurrayacine are reported. Asymmetric epoxidation of girinimbine led to (-)-trans-dihydroxygirinimbine and the assignment of its absolute configuration.
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