Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 9, Issue 20, Pages 7011-7015Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob06012k
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Funding
- Korea Research Foundation of Korean Government [2011-0004870]
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The selective signaling of hypochlorous acid by dithiolane-protected pyrene-aldehyde was investigated. Dithiolane derivative of pyrene-aldehyde was efficiently deprotected by hypochlorous acid to its corresponding aldehyde, which resulted in a prominent UV-vis and turn-on type fluorescence signaling. The signaling was not affected by the presence of other common alkali, alkaline earth metal ions, and anions. Interference from Hg(2+) ions could be successfully circumvented by using Chelex-100 resin. Dithiolane also provided selectivity toward hypochlorous acid over other commonly used oxidant of hydrogen peroxide.
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