Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 9, Issue 21, Pages 7535-7538Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob06297b
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- NSF
- MDS Research Foundation
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Synthesis of substituted 1,3-dienes was achieved via gold(I)-catalyzed Claisen rearrangement of allenyl vinyl ethers. The N-heterocyclic carbene gold chloride catalyst (IPrAuCl) was superior in terms of activity and selectivity and afforded the 3,3-product in excellent yields. A proposed cation-pi inter-action played a significant role in affecting the reaction rate.
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