Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 9, Issue 7, Pages 2069-2071Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob01178a
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Funding
- NRF [R31-2008-000-10029-0, 2010-0023127]
- NRF Priority Research Centers [2010-0029698]
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A facile method for the intermolecular Stetter reaction of various Michael acceptors with acetaldehyde as a biomimetic acylanion source was realized using N-heterocyclic carbene catalysis. This catalytic system has also been applied to the enantioselective Stetter reaction and resulted in moderate to good enantioselectivities for the corresponding Stetter products.
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