Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 9, Issue 12, Pages 4444-4447Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob05052d
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Funding
- DOE under ORNL
- Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy
- National Institutes of Health, Division of National Center for Research Resources [G12RR013459]
- National Science Foundation [CHE-0821357, CHE-0130835, CHE-1056927]
- University of Oklahoma
- NATIONAL CENTER FOR RESEARCH RESOURCES [G12RR013459] Funding Source: NIH RePORTER
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Structural characterization of a hydrogen sulfate complex with a tren-based urea suggests that the anion is coordinated with six NH center dot center dot center dot O bonds (d(N)center dot center dot center dot(O) = 2.857 (3) to 3.092 (3) angstrom) and one OH center dot center dot center dot O bond (d(O)center dot center dot center dot(O) = 2.57 (2) angstrom) from three receptors; however, in solution the anion is bound within the pseudo-cavity of one receptor.
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