Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 9, Issue 13, Pages 4882-4885Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob05527e
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- AstraZeneca
- EPSRC
- Pfizer
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CH activation and CH2 double activation of indolines at C2 may be achieved efficiently through radical translocation. The fate of the C2 indolinyl radical is dictated by the substitution at C3. Fragmentation, cyclisation and tandem cyclisation reactions leading to indole, azaheterocycle and azapropellane formation, respectively, are reported.
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