Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 8, Issue 3, Pages 511-521Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b920434b
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Funding
- Ministry of Education, Culture, Sports, Science and Technology of the Japanese Government
- MEXT-HITEC
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Herein, we describe Hg(OTf)(2) as a new catalytic system for organic synthesis, which can achieve the hydration of alkynes, C-C bond forming cyclizations, heterocycle synthesis and cyclization initiated by allylic alcohols at very high catalytic turnovers under mild conditions. The first solid-supported mercuric salt, silaphenylmercuric triflate, was also developed and found to act as a powerful catalyst for most Hg(OTf)(2)-catalyzed reactions.
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