Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 8, Issue 22, Pages 5074-5086Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00117a
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- CSIR, New Delhi
- NCL, Pune [MLP015826]
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A novel, practical and efficient enantioselective synthesis of sphingoid bases, L-threo-[2S,3S]-sphinganine (safingol), L-threo-[2S,3S]-sphingosine, L-arabino-[2R,3S,4R] and L-xylo-[2R,3S,4S]-C-18-phytosphingosine is described. The synthetic strategy features the Sharpless kinetic resolution and tethered aminohydroxylation (TA) as the key steps.
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