Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 8, Issue 24, Pages 5490-5494Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00448k
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- MNESR
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An efficient synthesis of deoxy-lambertellols was reported through a highly chemo-and diastereoselective intermolecular Diels-Alder cycloaddition between trans-1,2-disiloxybenzocyclobutenes and 2-methylprotoanemonine. Such transformation with delta-substituted gamma-alkylidenebutenolides, to prepare new analogues of these tricyclic spirolactones, which would be very difficult to prepare by other ways, was also studied.
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