Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 8, Issue 20, Pages 4524-4526Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00406e
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A highly efficient enantioselective alpha-amination of branched aldehydes with azadicarboxylates promoted by chiral proline-derived amide thiourea bifunctional catalysts was developed for the first time, affording the adducts bearing quaternary stereogenic centers with excellent yields (up to 99%) and enantioselectivities (up to 97% ee).
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