Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 8, Issue 17, Pages 3847-3850Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00174k
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Funding
- Natural Science Foundation of China [20902025]
- East China Normal University
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The direct alpha-cyanoamination of isatins using TMSCN has been developed, which is carried out in methanol without any catalyst. A new bifunctional cinchona alkaloid-based phosphinamide catalyst 7 could promote the Strecker reaction of isatins derived ketimine with TMSCN in up to 74% ee.
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