Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 8, Issue 18, Pages 4165-4168Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00054j
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- Agence Nationale de la Recherche (ANR) [06-Blan-0137]
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Chemoenzymatic dynamic kinetic resolution (DKR) of amines involving sulfanyl radical-induced racemization happened to be the very first switchable DKR process allowing the synthesis of either (R)- or (S)-amides, in good yield and high enantiomeric excess, depending on the nature of the enzyme; the different steps of the development of (S)-selective DKR are discussed.
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