Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 8, Issue 20, Pages 4518-4520Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00243g
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- MURST
- University La Sapienza
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A novel palladium-catalyzed synthesis of arylphosphonates from arenediazonium tetrafluoroborates and triethylphosphite or diethylphosphite is presented. The reaction tolerates useful substituents including bromo, chloro, nitro, ether, cyano, keto, and ester groups, can be performed as a one-pot process from anilines omitting the isolation of arenediazonium salts, and can be extended to the preparation of arylphosphine oxides and arylphosphines.
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