Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 8, Issue 6, Pages 1290-1292Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b924542a
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A concise, convergent synthesis of (+/-)-frondosin B has been developed based on the application of a Stille-Heck reaction sequence of 2-chloro-5-methoxybenzo[b]furan-3-yl triflate and 2-(3-butenyl)-3-(trimethylstannyl)cyclohex-2-enone giving the racemic natural product in a 34% overall yield.
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