Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 8, Issue 9, Pages 2212-2218Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b923393h
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- Deutsche Forschungsgemeinschaft [KO 1390/9-1]
- BMBF
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Cube-octameric silsesquioxane (POSS) based conjugation scaffolds for copper catalysed azide-alkyne [3+2] cycloaddition are reported. The synthetic route to octaazido and octaalkyno functionalised POSS templates without cage rearrangements is described. A set of click couplings is conducted including the first effective conjugation with a fully unprotected functional peptide towards a POSS assembled peptide octamer.
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