Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 7, Issue 9, Pages 1890-1895Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b823047a
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Funding
- National Natural Science Foundation of China [20532010, 20772128]
- Chinese Academy of Sciences
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A new type of supramolecular chiral dendritic monophosphite ligands has been prepared via a hydrogen-bonding assembly. The Rh complexes of these supramolecular ligands have been successfully applied in the asymmetric hydrogenation of enamides and dehydroamino acid derivatives with good enantioselectivities, which are comparable to those obtained from the free monophosphite ligands. The supramolecular catalyst could be easily recycled via solvent precipitation.
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