Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 7, Issue 20, Pages 4233-4240Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b910522k
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The affinity of new di-, tri- and tetrathiourea functionalised fused [3] and [5]polynorbornane based hosts 1-6 towards terephthalate(2)-was proportional to the size of the preorganised cleft/cavity imparted by the polynorbornane scaffold. Receptors based on the [5]polynobornane framework had greater affinities for the anion due to a higher degree of host: guest size complementarity. Hosts 1-5 formed 1: 1 host: guest complexes with the rigid dianion, yet remarkably, host 6 was found to bind two terephthalate guests.
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