4.6 Article

First synthesis and electronic properties of diphenothiazine dumbbells bridged by heterocycles

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 7, Issue 3, Pages 469-475

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b814850c

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Funding

  1. Deutsche Forschungsgemeinschaft DFG [1181]
  2. Deutscher Akademischer Austauschdienst DAAD
  3. Fonds der Chemischen Industrie

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According to cyclic voltammetry, symmetrical dumbbell-shaped phenothiazine dyads bridged by heterocycles show intense electronic coupling between the redox-active phenothiazine moieties. Furthermore, the fluorescence of the pyridyl-bridged derivatives can be controlled by pH change giving reversibly switchable redox-active biselectrophore dyads.

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