4.6 Article

Highly stereoselective synthesis of aminoglycosides via rhodium-catalyzed and substrate-controlled aziridination of glycals

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 7, Issue 7, Pages 1284-1287

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b823099b

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Funding

  1. Nanyang Technological University and Ministry of Education, Singapore

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The flexible installations of a sulfamate ester on a glycal scaffold at C3, C4, or C6 approaching alpha- or beta-aminoglycosides is communicated. A variety of glycal acceptors (O, S, and N) were applied, enhancing the utility of this method as an operationally simple protocol for the stereoselective synthesis of polyfunctionalized alpha- or beta-aminosaccharides.

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