Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 7, Issue 17, Pages 3379-3381Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b912128p
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Funding
- Swedish Research Council
- Swedish Foundation for Strategic Research
- K & A Wallenberg foundation
- German Academic Exchange Service (DAAD)
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Crude Porcine pancreatic lipase was successfully used for the kinetic resolution of axially chiral primary allenic alcohols providing very high enantioselectivities with E values above 200. This simple access to optically active allenes was applied to the total synthesis of the fungal metabolite (-)-striatisporolide A, allowing its unambiguous stereochemical assignment.
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